Electron Paramagnetic Resonance of d Transition Metal Compounds (Studies in Inorganic Chemistry)

Electron Paramagnetic Resonance of d Transition Metal Compounds (Studies in Inorganic Chemistry) by F.E. Mabbs

Title: Electron Paramagnetic Resonance of d Transition Metal Compounds (Studies in Inorganic Chemistry)
Author: F.E. Mabbs
ISBN10: 0444898522
ISBN13: 978-0444898524
Publisher: Elsevier Science; 1 edition (November 19, 1992)
Language: English
Subcategory: Chemistry
Size PDF: 1701 kb
Size Fb2: 1729 kb
Rating: 3.5/5
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Pages: 1326 pages
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Electron Paramagnetic Resonance of d Transition Metal Compounds (Studies in Inorganic Chemistry) by F.E. Mabbs


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Electron paramagnetic resonance (epr) spectroscopy is a sensitive and versatile method of studying paramagnets, which is finding increasing use in chemistry, biochemistry, earth and materials sciences.

The technique is treated both qualitatively and quantitatively, with a progressive increase in sophistication in each succeeding chapter. Following a general introductory chapter, the first half of the book deals with single unpaired electron systems and considers both metal and ligand Zeeman, hyperfine and quadrupole interactions. The simulation of these spectra is discussed, followed by the relationship between spin-Hamiltonian parameters and models of the electronic structures of paramagnets. The second half of the book treats multiple unpaired electron systems using the same philosophy. An introduction to the epr properties of cluster compounds and of extended exchanging systems is also given. There is a chapter on linewidths and lineshapes, and an extensive appendix containing much additional information. A wide-ranging library of simulated and experimental spectra is given, as well as graphical data which should aid spectrum interpretation. Each chapter contains key references and there is a substantial subject and keyword index.

This book is designed to teach epr spectroscopy to students without any previous knowledge of the technique. However, it will also be extremely useful to researchers dealing with paramagnetic d transition metals.